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What is Photocatalyst ?
Photo-Catalysis is defined as "acceleration by the presence of as
catalyst". A catalyst does not change in itself or is consumed in the
chemical reaction.
Chlorophyll of plants is a type of photocatalyst. Photocatalysis compared to
photosynthesis: chlorophyll captures sunlight to turn water and carbon dioxide
into oxygen and glucose, photocatalysis creates a strong oxidation agent to
breakdown any organic matter to carbon dioxide and water in the presence of a photocatalyst,
plus the UV rays from either the sun or an artificial light source (such as
fluorescent lights).
Mechanism
When photocatalyst titanium dioxide (TiO2) absorbs Ultraviolet (UV)
radiation from sunlight or an illuminated light source (fluorescent lamps), it
will produce pairs of electrons and holes.
The electron of the valence band of titanium dioxide becomes excited when
illuminated by light. The excess energy of this excited electron promotes the
electron to the conduction band of titanium dioxide thereby creating the
negative-electron (e-) and positive-hole (h+) pair. This stage is referred to
as the semiconductor's "photo-excitation " state. The energy
difference between the valence band and the conduction band is known as the '
Band Gap '. Wavelength of the light necessary for photo-excitation is:
1240 (Planck's constant, h) / 3.2 ev (band gap energy) = 388 nm
The positive-hole of titanium dioxide breaks apart the water molecule to
form hydrogen gas and hydroxyl radical. The negative-electron reacts with
oxygen molecule to form a super oxide anion. This
cycle continues when light is
available.
Photocatalytic Oxidation
The most powerful advanced oxidation systems are based on the generation of
hydroxyl radicals. The hydroxyl radical is an extremely powerful oxidation
agent, second only to Fluorine in power (2.23 in Relative Oxidizing Power).
Following is a listing of common chemical oxidants, placed in the order of
their oxidizing strength:
|
Compound |
|
Oxidation Potential
(volts) |
|
Hydroxyl Radical |
|
2.8 |
|
Sulfate Radical |
|
2.6 |
|
Ozone |
|
2.1 |
|
Hydrogen Peroxide |
|
1.8 |
|
|
|
|
|
Chlorine Dioxide |
|
1.5 |
|
Chlorine |
|
1.4 |
|
Oxygen |
|
1.2 |
|
Bromine |
|
1.1 |
|
Iodine |
|
0.76 |
Utilizing the strong oxidation strength of hydroxyl radical, photocatalytic
oxidation can effectively disinfect, deodorize, and purify air, water, and
different surface areas.
Super-Hydrophilic
When
the surface of photocatalytic film is exposed to light, the contact angle of
the photocatalyst surface with water is reduced gradually. After enough
exposure to light, the surface reaches super-hydrophilic. In other words, it
does not repel water at all, so water cannot exist in the shape of a drop, but
spreads flatly on the surface of the substrate: water takes the form of a
highly uniform thin film, which behaves optically like a clear sheet of glass.
The
hydrophilic nature of titanium dioxide, coupled with the gravity, will
enable the dust particles to be swept away following the water stream, thus
making the product self-cleaning.
Why is Green Quest photocatalyst treatment
semi-permanent?
Although it is originally water-soluble, it dries quickly after application
and becomes water-insoluble. It also becomes as hard as a 4H pencil in ten to
fourteen days after application. It does not come off unless the surface is
polished. Even a bathroom can be used immediately after application. Because
titanium oxide is merely a catalyst and is not changed, its effect is
semi-permanent except when walls and ceilings are repainted, or if a strong
cleaning agent is used.
How long does Green Quest photocatalyst treatment last after
application?
Since photocatalyst TiO2 is only acting as semi-conductor catalyst, it
is not consumed during the oxidation process, therefore, completing a long
lasting oxidation cycle. Green Quest is now offering a five years product and
services warranty.
Is Green Quest photocatalyst treatment safe?
Yes , it will be no harm of direct touching the material or
having direct contact with it after its drying time. The material is totally
safe and the titanium dioxide used is FDA approved (refer to EPA certified
toxicity lab report).
Where can Green Quest photocatalyst treatments be applied?
Green Quest provides photocatalyst surface coating for long-lasting
effects of deodorization, sterilization, and anti-soiling purposes. Using our
specialized spray-coating equipments, a fine mist of
photocatalyst can be
applied on different types of surface materials achieving a guaranteed result.
In Automobiles, Building
Exteriors
Photocatalyst can deodorize the interior and gives the driver and passengers a
more pleasant driving experience. Odors embedded in the carpet and seats will
eventually be decomposed and rid the car these unpleasant odors.
- Company Cars
Public transportation (buses, trains, airplanes, taxis)
Rental cars
Limousines
Green Quest's Nano-TiO2 Photocatalyst can be applied on the exterior of a
building to treat and prevent unsightly damages caused by acid rain, moisture,
and smog. It cuts down on the overall maintenance cost and time.
- Hotels and motels
High-rise buildings
Apartments
Condos
Commercial business complexes
Green Quest's Nano-TiO2 Photocatalyst decomposes odor molecules caused by
tobacco smoke, pets, chemicals in detergents, urine and fecal matters.
Photocatalyst will continuously deodorize your living space and eliminates the
sources of your malodors.
- Restaurant
Public restrooms
Hotel and motel rooms
Senior Centers
Shops and animal
hospitals
- With a constant amount of
light provided, Green Quest's Nano-TiO2 photocatalyst can control and
prevent the growth of bacteria, germ, and mold. Any harmful bacteria and
germ would be killed and eventually be decomposed in this sterilized
condition.
- Hospital
Schools
Public Restrooms
Restaurant
Day-Care centers
How does Green Quest photocatalyst treatment compare to
traditional air purification system?
HEPA (High Efficiency Particle Arresting) Filter
Most widely known method for purifying air. Depending on the filter size, it
can clean up to 99.99% of particulate in the air with proper ventilation. They
are not effective on treating mold, mildew, bacteria, and other fungi.
Electrostatic Filtration
Another filtration system with a negatively charged surface is used to attract
particulates. In comparison to most HEPA systems it is more effective in
trapping smaller micron particulates and is effective in clearing smoke from
the air. Low levels of ozone may be produced which can neutralize most mold,
mildew, bacteria, and other fungi that comes in contact with the filter.
Ionization
Also uses a negatively charged surface to produce and expel an abundance of
negative ions and cause suspended particles to cling to walls, floors, and
other surfaces . Most ionizes are effective in settling dust and particulates
out of our breathing space.
Ozone
Ozone is a very powerful oxidizer that will neutralize odors, mold, mildew,
bacteria, and other fungi. This technology is commonly used in flood and fire
restoration. Ozone is found to be effective because it works on the problem at
the source and air does not have to be pulled through the unit for treatment.
UV Germicidal Lamps
Commonly used for disinfectant purposes. This technology is effective in
sterilizing air and surfaces that come in contact with the UV light. UV has
been proven in both air and water applications to inactivate bacteria and
viruses to prevent them from reproducing.
Photocatalysis
Using light to react with a catalyst resulting in oxidation. This is found
to be effective in destroying mold, mildew, bacteria, other fungi, dust mites,
and many odors. This technology is produced with an Ozone/UV lamp set in a
variety of combinations. When this type of photocatalysis is combined with the
natural humidity in indoor air, it creates hydroxyl radicals and super oxide
ions that are effective in combating bacteria, fungi and VOCs(volatile organic
compounds). This method is also a pro-active approach that goes to the source
for treatment.
|
Item |
Hepa Filter |
Electrostatic |
Ozone |
UV |
Ionizer |
Photocatalysis |
|
Mold |
Poor |
Good |
Good |
Good |
Poor |
Excellent |
|
Bacteria |
Poor |
Good |
Good |
Good |
Poor |
Excellent |
|
Dust Mites |
Poor |
Poor |
Poor |
Good |
Poor |
Excellent |
|
Gases |
Poor |
Poor |
Good |
Good |
Poor |
Excellent |
|
Odors |
Poor |
Good |
Good |
Poor |
Good |
Excellent |
|
Smoke |
Good |
Good |
Good |
Poor |
Excellent |
Good |
|
VOCs |
Poor |
Poor |
Good |
Good |
Poor |
Excellent |
|
Pet Dander |
Good |
Good |
Good |
Good |
Good |
Excellent |
What factors may influence the efficiency of Green Quest photocatalyst
treatment?
Light and airflow will have a remarkable influence over the reaction
of the photocatalyst. Both factors are needed to maintain the coating
effectiveness all the time. From that, the better airflow you have (air
circulation which can be obtained by using an ordinary fan or the normal air
movement from central air) and the longer light times, the better the results
will be.
What is Indoor Air Pollution?
Research indicates that people spend approximately 80 ~ 90 percent of their
time indoors, where they are exposed to polluted indoor air that may cause
irritation of the eyes, nose, and throat, headaches, dizziness, fatigue, and
even lung cancer or other malignancies. Recent studies reveal that bacteria,
molds and house dust mites are breeding inside carpets and air conditioners and
can be airborne by dust particles. Paints, varnishes, harmful chemical fibers
and pressed wood products, which are most commonly used in household decoration,
may emit formaldehyde, benzene and other hazardous and carcinogenic organic
chemicals -- all these as well as unwholesome matters produced in the
metabolism of human bodies and the ammonia inside toilets have made the air
within homes and buildings more seriously polluted than the outdoor air.
People may experience one or more of
the following reactions when exposed to indoor air pollution:
Allergic Reactions
Some common signs and symptoms are:
· Watery eyes
· Runny nose and sneezing
· Nasal congestion
· Itching
· Coughing
· Wheezing and difficulty breathing
· Headaches
· Fatigue
Infectious Reactions
Caused by bacteria and viruses, such as influenza, measles, chicken pox, and
tuberculosis. Most infectious diseases pass from person to person through
physical contact. Crowded conditions with poor air circulation can promote the
spread of infectious diseases. Some bacteria and viruses thrive in buildings
and circulate through indoor ventilation systems that have poor filtration
systems in place or are not serviced regularly.
Toxic Reactions
Some fungi are known to produce toxic substances as a by-product of their
metabolism, which can cause a variety of adverse health effects. Short-term
symptoms can include dermatitis, respiratory irritation, headaches and fatigue.
Long-term health effects can include cancer, damage to the central nervous
system, and suppression of the immune system.
The U.S. Environmental Protection Agency ranks poor indoor air quality among
the top five environmental risks to public health. Poor indoor air quality can
cause or contribute to the development of chronic respiratory diseases such as
asthma and pneumonitis. In addition, it can cause headaches, dry eyes, nasal
congestion, nausea and fatigue. People who already have respiratory diseases
are at greater risks.
What is Sick
Building Syndrome?
The term " sick building syndrome " (SBS) is used to
describe situations in which building occupants experience acute health and
comfort effects that appear to be linked to time spent in a building, but no
specific illness or cause can be identified.
you
know …
Indoor
Air is up to 100 times worse than outdoor air (American College of Allergists)
50%
of all illness is caused by indoor air pollution (Environmental Protection
Agency)
Indoor
Air Pollution is America’s Number One Environmental Health Concern
(Environmental Protection Agency to the U.S. Senate, November 1996)
Indoor
Air Pollution is wide spread. You are more likely to get sick from pollution in
your
home and office than from pollution in the air outside. (The American Lung
Association)
Americans
spend approximately 90% of their time indoors. Now the leading chronic illness
among children, asthma affects one in ten children. Yale
School of Medicine
Lost
productivity associated with indoor air pollution costs businesses an estimated
$60 billion per year. Environmental Protection Agency
People
are getting sick just by staying indoors, where we thought it’s safe.
If
you are suffering from:
Eye irritation caused by sensation of dryness and redness
Chronic Respiratory Illness and Asthma
Dryness and irritation of the throat
Headaches, lethargy, fatigue, and poor concentration
Skin irritation caused by dryness and rash
You might be a victim of Sick Building Syndrome!!!
Sick Building Syndrome is used to describe
situations in which building occupants experience acute health and comfort
effects that appear to be linked to time spent in a building, but no specific
illness or cause can be identified. Often, the only common denominator of
Sick Building Syndrome is insufficient ventilation air to remove the
contaminants.
In
some new buildings the problem can be the use of synthetic materials (such as
insulation or carpeting) which release hydrocarbons or other vapors into the
air at a very low rate. The solution in this case may be to remove the
offending material and replace it with an acceptably innocuous alternative.
Some
of the typical pollutants from synthetic materials are:
Formaldehyde – Building material,
smoking, household products, and fuel-burning appliances
Carbon
Monoxide –
Gas heaters, leaking chimneys and furnaces, gas water heaters, wood stove, gas
stoves, gasoline-powered equipments, automobile exhaust and tobacco smoke.
Volatile
Organic Compound
– Paint, paint strippers, solvents, wood preservatives, aerosol sprays,
cleansers and disinfectants, moth repellents, air fresheners, stored fuels and
automotive products, hobby supplies, and dry-cleaned clothing
Nitrogen
Dioxide
– Heaters, un-vented gas stoves and heaters, and environmental tobacco smoke.
Sometimes
the problem is caused by various microbial growths. Bacteria, molds, pollen,
and viruses are types of biological contaminants. These contaminants may breed
in stagnant water that has accumulated in ducts, humidifiers and drain pans, or
where water has collected on ceiling tiles, carpeting, or insulation. Physical
symptoms related to biological contamination include cough, chest tightness,
fever, chills, muscle aches, and allergic responses such as mucous membrane
irritation and upper respiratory congestion.
The following have been cited causes of or contributing factors to sick
building syndrome:
1. Inadequate ventilation
In an effort to achieve acceptable Indoor Air Quality or IAQ while minimizing
energy consumption, the American Society of Heating, Refrigerating and
Air-Conditioning Engineers (ASHRAE) recently revised its ventilation standard
to provide a minimum of 15 cfm of outdoor air per person (20 cfm/person in office
spaces). Up to 60 cfm/person may be required in some spaces (such as smoking
lounges) depending on the activities that normally occur in that space.
2. Chemical contaminants from indoors sources
Most indoor air pollution comes from sources inside the building. For
example, adhesives, carpeting, upholstery, manufactured wood products, copy
machines, pesticides, and cleaning agents may emit volatile organic compounds
(VOCs), including formaldehyde. Environmental tobacco smoke contributes high
levels of VOCs, other toxic compounds, and repairable particulate matter.
Research shows that some VOCs can cause chronic and acute health effects at
high concentrations, and some are known carcinogens. Low to moderate levels of
multiple VOCs may also produce acute reactions. Combustion products such as
carbon monoxide, nitrogen dioxide, as well as respirable particles, can come
from unvented kerosene and gas space heaters, wood stoves, fireplaces and gas
stoves.
3. Chemical contaminants from outdoor sources
The outdoor air that enters a building can be a source of indoor air pollution.
For example, pollutants from motor vehicle exhausts, plumbing vents, and
building exhausts (e.g., bathrooms and kitchens) can enter the building through
poorly located air intake vents, windows, doors, and other openings. In
addition, combustion products and pollution can enter a building from a nearby
garage, traffic from a busy street or highway, or a car that is idling.
4. Biological contaminants
Bacteria, molds, pollen, and viruses are types of biological contaminants.
These contaminants may breed in stagnant water that has accumulated in ducts,
humidifiers and drain pans, or where water has collected on ceiling tiles,
carpeting, or insulation. Physical symptoms related to biological contamination
include coughing, chest tightness, fever, chills, muscle aches, and allergic
responses such as mucous membrane irritation and upper respiratory congestion.
Other Significant Usages
for Photocatalysis
1. Anti-Bacterial Effect
Photocatalyst does not only kill bacteria cells, but also decompose the cell
itself. The titanium dioxide photocatalyst has been found to be more effective
than any other antibacterial agent, because the photocatalytic reaction works
even when there are cells covering the surface and while the bacteria are
actively propagating. The end toxin produced at the death of cell is also
expected to be decomposed by photocatalytic action. Titanium dioxide does not
deteriorate and it shows a long-term anti-bacterial effect. Generally speaking,
disinfections by titanium oxide is three times stronger than chlorine, and 1.5
times stronger than ozone.
2. Deodorizing Effect
On the deodorizing application, the hydroxyl radicals accelerate the
breakdown of any Volatile Organic Compounds or VOCs by destroying the molecular
bonds. This will help combine the organic gases to form a single molecule that
is not harmful to humans thus enhance the air cleaning efficiency. Some of
the examples of odor molecules are: Tobacco odor, formaldehyde, nitrogen
dioxide, urine and fecal odor, gasoline, and many other hydro carbon molecules
in the atmosphere.
Air purifier with Ti02 can prevent smoke and soil, pollen, bacteria, virus
and harmful gas as well as seize the free bacteria in the air by a filtering
percentage of 99.9% with the help of the highly oxidizing effect of
photocatalyst (Ti02).
3. Air Purifying Effect
The photocatalytic reactivity of titanium oxides can be applied for the
reduction or elimination of polluted compounds in air such as NOx, cigarette
smoke, as well as volatile compounds arising from various construction
materials. Also, high photocatalytic reactivity can be applied to protect
lamp-houses and walls in tunneling, as well as to prevent white tents from
becoming sooty and dark. Atmospheric constituents such as chlorofluorocarbons
(CFCs) and CFC substitutes, greenhouse gases, and nitrogenous and sulfurous
compounds undergo photochemical reactions either directly or indirectly in the
presence of sunlight. In these polluted areas, the pollutants can eventually be
removed.
4. Anti fogging, Self-Cleaning
Most of the exterior walls of buildings become soiled from automotive
exhaust fumes, which contain oily components. When the original building
materials are coated with a photocatalyst, a protective film of titanium
provides the self-cleaning building by becoming antistatic, super oxidative,
and hydrophilic. The hydrocarbon from automotive exhaust is oxidized and the
dirt on the walls washes away with rainfall, keeping the building exterior
clean at all times.
5. Water Purification
Photocatalyst coupled with UV lights can oxidize organic pollutants into
nontoxic materials. CO2 and water and can disinfect certain bacteria. This
technology is very effective at removing further hazardous organic compounds
(TOCs) and at killing a variety of bacteria and some viruses in the secondary
wastewater treatment. Pilot projects demonstrated that photocatalytic
detoxification systems could effectively kill fecal coli form bacteria in secondary
wastewater treatment.
Lab Results:
Researches from institutions:
NASA - SpaceResearch - Securing the Home Planet
Reducing
MeBr Emissions with a Sheet Containing Titanium Dioxide
Industrial
Reviews:
CNN - Shuttle experiment leads to longer-lasting produce ...
Annihilating
Anthrax
CUHK
Research in Nanotechnology Serves the Community
New Pollutant Cleanup Technique Puzzles, Pleases Chemists
Nanotechnology:
A new world of Matter
UW Clean-Air Technology Headed For The Produce Section
Technology Breakthrough -
Green Quest's Photocatalyst Products
are truly the breakthrough in dispersing nano-sized Titanium Dioxide in aqueous
form. Using their patented manufacturing process and chemical formula, Green Quest's Photocatalyst products
are neutral in ph and contain no
VOCs. Titanium Dioxide particles in Green
Quest’s products would not form any deposits which would prolong left
expectancy (residuals) of the product.
|
Green
Quest's
Photocatalyst |
Comparison
Categories |
Other
Photocatalyst
Products |
|
Light
Yellow Color |
Appearance |
Milky
White |
|
Neutral |
pH
Level |
Acidic |
|
Long-term
stability |
Stability |
Easy
to deteriorate |
|
Pure
water |
Additives |
Acid
and other organic solvents |
|
10
nm, high surface area |
Particle
Size |
20-30
nm |
|
Room
Temperature |
Membrane-forming
temperature |
Above
500C |
|
Excellent |
Membrane
density |
Poor |
|
most
organic and inorganic materials |
Applicability |
Limited
to acidic-proof and fire-proof materials |
Photocatalyst is now available from Innovative
Sealing Solutions, Inc.
which is a licensed member of Micro MED.
Green Quest is a subdivision of Micro MED. |